The glass transition in linear low density polyethylene determined by thermally stimulated depolarization currents

Author(s):  
E. Laredo ◽  
N. Suarez ◽  
A. Bello ◽  
L. Marquez
2013 ◽  
Vol 734-737 ◽  
pp. 2252-2255
Author(s):  
Fang Wei Qi ◽  
Xue Gang Luo ◽  
Xiao Yan Lin ◽  
Si Zhao Zhang

In this article, calcium carbonate filled linear low density polyethylene (LLDPE) was prepared and the influences of particle size and size distribution on the rheological and mechanical properties of the composites were investigated. The results showed that the glass transition and thermal decomposition temperatures of LLDPE phase in LLDPE/CaCO3composites were shifted toward higher temperatures by the restriction of CaCO3particles on the segmental and long-range chain mobility of the LLDPE phase. The composites showed shear thinning behaviors and the viscosity decreased with the rational size and size distribution. Additionally, the elongation at break notably improved to some extent.


2019 ◽  
Vol 796 ◽  
pp. 22-29
Author(s):  
N.A. Ahmad ◽  
Shaifulazuar Rozali ◽  
Mohd Faizul Mohd Sabri ◽  
C.Y. Chee ◽  
Suriani Ibrahim

Blended polymer composites are prepared based on linear low density polyethylene (LLDPE) and mixed with polysulfone (PSU) using solvent casting technique. LLDPE is functionalized with carbonyl functional groups to enable it to interact with PSU from the molecular level. Various weight percent of PSU is added into LLDPE to find the optimum weight percent ratio between LLDPE and PSU. The highest glass transition temperature obtained is 47.58°C for ratio LLDPE to PSU of 7:3. In addition, value for decomposition temperature is increased up to 490.16°C with the increasing of PSU content. SEM observation of the blended polymer films shows that glass transition and decomposition temperature depend on morphology of the blended polymers.


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1537
Author(s):  
Luděk Hynčík ◽  
Petra Kochová ◽  
Jan Špička ◽  
Tomasz Bońkowski ◽  
Robert Cimrman ◽  
...  

Current industrial trends bring new challenges in energy absorbing systems. Polymer materials as the traditional packaging materials seem to be promising due to their low weight, structure, and production price. Based on the review, the linear low-density polyethylene (LLDPE) material was identified as the most promising material for absorbing impact energy. The current paper addresses the identification of the material parameters and the development of a constitutive material model to be used in future designs by virtual prototyping. The paper deals with the experimental measurement of the stress-strain relations of linear low-density polyethylene under static and dynamic loading. The quasi-static measurement was realized in two perpendicular principal directions and was supplemented by a test measurement in the 45° direction, i.e., exactly between the principal directions. The quasi-static stress-strain curves were analyzed as an initial step for dynamic strain rate-dependent material behavior. The dynamic response was tested in a drop tower using a spherical impactor hitting a flat material multi-layered specimen at two different energy levels. The strain rate-dependent material model was identified by optimizing the static material response obtained in the dynamic experiments. The material model was validated by the virtual reconstruction of the experiments and by comparing the numerical results to the experimental ones.


2015 ◽  
Vol 37 (11) ◽  
pp. 3167-3174 ◽  
Author(s):  
S. Sánchez-Valdes ◽  
E. Ramírez-Vargas ◽  
L.F. Ramos de Valle ◽  
J.G. Martinez-Colunga ◽  
J. Romero-Garcia ◽  
...  

1988 ◽  
Vol 27 (2) ◽  
pp. 172-178 ◽  
Author(s):  
S. Ottani ◽  
A. Valenza ◽  
F. P. La Mantia

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